Molecular probes of the mechanism of cytochrome P450. Oxygen traps a substrate radical intermediate
نویسندگان
چکیده
منابع مشابه
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Hypersensitive radical probes and the mechanisms of cytochrome P450-catalyzed hydroxylation reactions.
The title probes are precursors to kinetically calibrated, aryl-substituted cyclopropylcarbinyl radicals that rearrange with picosecond lifetimes. Applications in studies of cytochrome P450-catalyzed hydroxylation reactions are reviewed. Initially confusing results regarding lifetimes of radicals in the hydroxylation reactions were resolved when second-generation probes that distinguish between...
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ژورنال
عنوان ژورنال: Archives of Biochemistry and Biophysics
سال: 2011
ISSN: 0003-9861
DOI: 10.1016/j.abb.2010.11.001